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Paper   IPM / Nano-Sciences / 14633
School of Nano Science
  Title:   Functionalization of fullerene at room temperature: toward new carbon vectors with improved physicochemical properties
1.  Z. Beiranvand
2.  A. Kakanejadifard
3.  I. S. Donskyi
4.  A. Faghani
5.  Z. Tu
6.  A. Lippitz
7.  Pezhman Sasanpour
8.  F. Maschietto
9.  B. Paulus
10.  W. E. S. Unger
11.  R. Haag
12.  M. Adeli
  Status:   Published
  Journal: RSC Adv.
  No.:  114
  Vol.:  6
  Year:  2016
  Pages:   112771
  Publisher(s):   The Royal Society of Chemistry
  Supported by:  IPM
In this work, fullerene has been functionalized with cyanuric chloride at room temperature by a nitrene mediated [2 + 1] cycloaddition reaction. The adduct after functionalization is inherently in the form of azafulleroid and shows broad UV absorption in the wavelength range of 200-800 nm, as well as photothermal conversion and fluorescence with a high quantum yield.

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